Chlorine in RO Systems
Purpose: Used in pre-treatment to disinfect feed water.
Function: Kills bacteria, algae, and oxidizes organic contaminants.
Limitation: RO membranes (polyamide type) are highly sensitive to chlorine; prolonged exposure causes oxidative degradation and reduces salt rejection.
Phase: Applied before filtration.
🧪 SMBS (Sodium Metabisulfite) in RO Systems
Purpose: Acts as a dechlorination agent before water enters RO membranes.
Function: Neutralizes residual chlorine, preventing oxidation damage.
Reaction:
Phase: Applied after chlorination and filtration, just before RO membranes.
🔄 Operational Sequence
Raw water chlorination → microbial control.
Filtration (sand/carbon filters) → removes solids and some chlorine.
SMBS dosing → neutralizes remaining chlorine.
RO membrane feed → chlorine-free water for safe operation.
📊 Comparison Table
| Parameter | Chlorine | SMBS |
|---|---|---|
| Purpose | Disinfection | Dichlorination |
| Phase Used | Pre-treatment | Before RO membranes |
| Effect on Membrane | Damaging (oxidation) | Protective |
| Chemical Nature | Oxidizing agent | Reducing agent |
| Dosage Control | 1–2 ppm | 2–3 ppm (stoichiometric excess) |
| Monitoring | Residual chlorine test | ORP/DPD test for zero chlorine |
Chlorine ensures microbial control upstream.
SMBS ensures membrane protection downstream. Together, they form a balanced chemical strategy for RO system reliability and water quality.
Full Image Reference: Here is the detailed schematic comparing Chlorine vs SMBS in RO Systems:
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